Electrochemical sensor and method for the production thereof

ABSTRACT

The present invention relates to an electrochemical sensor, which has a sensor element ( 10 ), and is used to determine a gas concentration of a gas to be analyzed. The sensor element ( 10 ) has a first solid electrolyte layer ( 30 ), an electrode ( 34 ) that includes an electrode surface ( 32 ) and an electrode lead ( 33 ), and a second solid electrolyte layer ( 40 ); a gas channel ( 31 ) being introduced into the first solid electrolyte layer ( 30 ) in such a manner, that the electrode ( 34 ) is situated in a first, clamped region ( 50 ) between the first and the second solid electrolyte layers ( 30, 40 ), and in a second, open region ( 51 ) between the second solid electrolyte layer ( 40 ) and the gas compartment ( 31 ). In a transition region ( 52 ) between the clamped region ( 50 ) and the open region ( 51 ), the electrode ( 34 ) borders on a layer pattern, which is constructed in such a manner, that the electrode ( 34 ) is subjected to a lower pressure during a laminating procedure.

BACKGROUND OF THE INVENTION

[0001] The present invention is based on an electrochemical sensor according to the definition of the species in claim 1.

[0002] Such electrochemical sensors are known, for example, from the Automotive Electronics Handbook (1994), chapter 6, Wiedenmann et al., “Exhaust Gas Sensors”, for use in analyzing exhaust gas of internal combustion engines. Such sensors include a planar sensor element, which is manufactured by the printing ceramic foils onto it, which have electrodes, by laminating the planar sensor element together using a compression force applied by means of a compression pad, and by sintering it. In the case of these sensor elements, there is, however, the danger of the electrode adjacent to the one gas channel being partially or completely severed during lamination, by the use of the compression force, so that normal use is impaired or excluded.

SUMMARY OF THE INVENTION

[0003] In comparison with the related art, the electrochemical sensor of the present invention, possessing the characterizing features of the independent claims, has the advantage of ensuring to the greatest possible extent, that the electrode or the electrode leads are routed continuously, without being pinched or broken, even in a transition region between the gas channel and adjacent solid electrolyte foils.

[0004] By selecting a suitable layer pattern in the transition region of the electrode, the electrode present in the laminating process in the form of a paste is subjected to a lower pressure, so that the pinching of the electrode in the clamped region and the transport of the electrode into the open region are prevented to the greatest possible extent. Therefore, a reduction in the cross-sectional area of the electrode in the transition region, or even a complete separation of the electrode, is prevented, which means that a lower production variance is achieved, e.g. with regard to the electrical resistance of the electrode, and less manufacturing waste is generated.

[0005] The method of the present invention for manufacturing an electrochemical sensor ensures that a lower local pressure is applied to the electrode while laminating it together, and therefore, that the electrode is produced in a manner allowing it to be unpinched and unbroken to the greatest possible extent.

[0006] Advantageous further refinements of the sensor specified in the main claim are rendered possible by the measures given in the dependent claims.

BRIEF DESCRIPTION OF THE DRAWING

[0007] The present invention is explained in light of the drawing and the subsequent description. The figures show:

[0008]FIG. 1 an exploded view of a specific embodiment of a sensor element according to the related art;

[0009]FIG. 2 a plan view of a solid electrolyte foil of the sensor element according to the related art;

[0010]FIG. 3 a plan view of a solid electrolyte foil of the present invention's sensor element, according to a first specific embodiment;

[0011]FIG. 4 a plan view of the solid electrolyte foil, in accordance with a further embodiment of the sensor element of the present invention;

[0012]FIG. 5a a sectional view of the sensor element according to the related art, along line V-V in FIG. 2; and

[0013]FIG. 5b to 5 d in each instance, a detail B of FIG. 5a, in accordance with specific embodiments of the present invention.

DESCRIPTION OF THE EXEMPLARY EMBODIMENTS

[0014]FIG. 1 shows a planar sensor element 10 of an electrochemical sensor for analyzing gases, which is known per se from the related art. Sensor element 10 has electrical connection contacts 20, a first solid electrolyte foil 30 in which a gas channel 31 is formed that is connected, on the terminal end, via an opening, to a gas compartment situated outside sensor element 10, an electrode 34 as a reference electrode which includes an electrode surface 32 and an electrode lead 33, a foil binding layer 35, a second solid electrolyte foil 40, a measuring electrode 41, and a covering layer 42, as well as a further solid electrolyte foil 21 as a heater foil, a first insulating layer 22, a heater 23, and a further insulating layer 24. Solid electrolyte foils 21, 30, 40 can also be manufactured as solid electrolyte layers.

[0015]FIG. 2 shows the known sensor element according to FIG. 1, as a plan view of the large surface of second solid electrolyte foil 40, along with foil-bonding layer 35 and electrode 34. Electrode 34 is situated in a first, clipped region 50, between first solid electrolyte foil 30 and second solid electrolyte foil 40, and in a second, open region 51, between gas channel 31 and second solid electrolyte foil 40. The position of gas channel 31 is indicated by dotted lines.

[0016]FIG. 3 shows a first exemplary embodiment of the present invention, whereby, in a revision of the known design according to FIG. 2, foil-bonding layer 35 is left out in transition region 52, between clamped region 50 and open region 51 of electrode 34. Other designs are conceivable, in which electrode 34 is surrounded by at least one further foil-bonding layer that is also left out in transition region 52. In the case of a plurality of foil-bonding layers, the recesses can be set up step-by-step. By leaving out at least one foil-bonding layer 35, the height of the material between first and second solid electrolyte layers 30, 40 is reduced in transition region 52, which means that, during lamination, a lower pressure is applied to electrode 34 in transition region 52.

[0017]FIG. 4 shows a plan view of a further exemplary embodiment according to the present invention, where, in a modification of the known design according to FIG. 2, electrode 34 is considerably wider along the boundary between first region 50 and second region 51, than in the region of gas channel 31. This reduces the danger of electrode 34 separating in transition region 52.

[0018]FIG. 5a shows a sectional view of the transition region 52 of electrode 34, for a sensor element according to FIG. 1, which is known per se. It is clear from the sectional view, that electrode lead 33 is pinched at the edge of gas channel 31, between solid electrolyte foils 30 and 40; in response to a high compression force, the edge being able to cut through electrode lead 33 at this position.

[0019]FIGS. 5b through 5 d shows specific embodiments of transition region 52 according to the present invention. In FIGS. 5b and 5 c, a recess 60 accommodating electrode lead 33 is imprinted into first solid electrolyte layer 30 and second electrolyte layer 40, respectively. Represented in FIG. 5d is a specific embodiment, which has a compensating layer 61 next to electrode lead 33. The layer patterns of the specific embodiments of transition region 52 shown in FIGS. 5b through 5 d prevent electrode lead 33 from being pinched during the laminating procedure.

[0020] In further embodiments of the present invention, which are not shown, recess 60 or compensating layer 61 can be finished in steps, whereby, during lamination, a more uniform pressure distribution on electrode 34 is achieved in transition region 52.

[0021] In another specific embodiment, which is not represented in further detail, transition region 52 is placed in a region of the sensor element, in which gas channel 31 is particularly narrow, e.g., in the case of the sensor element 10 shown in FIG. 2, not in measuring-end region 62 having a wide gas channel 31, but rather in terminal-end region 63 having a narrow gas channel 31. This reduces the local pressure in the transition region, during lamination.

[0022] Equally conceivable is a specific embodiment having an arbitrary combination of the measures specified in the dependent claims.

[0023] In a development of the present invention regarding the method for manufacturing the sensor element of the present invention, a hard compression pad is used during lamination, so that a pressure increase in the area of gas channel 31, and thus, in transition region 52, is prevented during lamination. 

What is claimed is:
 1. An electrochemical sensor for determining gas components and/or gas concentrations in gas mixtures, having a sensor element which has a first solid electrolyte layer, an electrode that includes an electrode surface and an electrode lead, and a second solid electrolyte layer; a gas channel being introduced into the first solid electrolyte layer in such a manner, that the electrode is situated in a first, clamped region between the first and the second solid electrolyte layers, and in a second, open region between the second solid electrolyte layer and the gas compartment, wherein the electrode (34) borders on a layer pattern in a transition region (52) between the clamped region (50) and the open region (51), the layer pattern being constructed in such a manner, that the electrode (34) is subjected to a lower pressure during a laminating procedure.
 2. The sensor as recited in claim 1, wherein at least one foil-bonding layer (35) is situated between the electrode (34) and the first or second solid electrolyte layer (30, 40), and, in the transition region (52), at least one foil-bonding layer (35) provided per se is left out.
 3. The sensor as recited in claim 1, wherein, in the transition region (52), the first and/or the second solid electrolyte layer (30, 40) has a preferably stamped recess (60) for the electrode (34).
 4. The sensor as recited in claim 1, wherein, in the transition region (52), a compensating layer (61) is situated next to the electrode (34).
 5. The sensor as recited in one of the preceding claims, wherein the layer pattern is constructed in steps.
 6. The sensor as recited in claim 1, wherein the transition region (52) is placed in a region of the sensor element (10), in which the surface area of the gas channel (31) is low.
 7. The sensor as recited in claim 1, wherein the electrode (34) is markedly wider along the boundary between the first and the second regions (50, 51), than in the region of the gas channel (31).
 8. A method for manufacturing an electrochemical sensor as recited in at least one of the preceding claims, the sensor element (10) being manufactured by pressing it, laminating it together using a compression force applied by a compression pad, and by sintering it, wherein a lower pressure is applied to the electrode (34) during lamination.
 9. The method as recited in claim 8, wherein a hard compression pad is used during lamination. 